Federal Government Technical Report Properties, Composition and Marine Spill Behaviour, Fate and Transport of Two Diluted Bitumen Products from the Canadian Oil Sands

This report is currently available at http://crrc.unh.edu/sites/crrc.unh.ed/file/1633_dilbit_technical_report_e_v2_final-s.pdf

Federal Government Technical Report
Properties, Composition and Marine Spill Behaviour, Fate and
Transport of Two Diluted Bitumen Products from the Canadian
Oil Sands
Environment Canada
Emergencies Science and Technology
Fisheries and Oceans Canada
Centre for Offshore Oil, G
as and Energy Research
Natural Resources Canada
Canmet ENERGY
November 30, 2013
Executive Summary
Effective spill response depends on good scientific understanding of petroleum product behaviour in the environment (e.g., movement and changes in physical properties and chemical composition of the oil). This study reports the early research simulating diluted bitumen products spilled at sea. This work was undertaken by the Government of Canada as part of the first phase of a strategy to implement a world class prevention, preparedness and response regime for oil spills from ships.
The behaviour of the diluted bitumen products was studied under laboratory conditions in three phases. First, the properties and composition of two samples representative of products currently being shipped in Canada were measured before (fresh) and after (weathered) exposure to environmental conditions. Secondly, the potential for evaporation, exposure to light, mixing with saltwater, and sediments in the salt water to affect whether diluted bitumen products float or sink
in saltwater was examined. Finally, the effectiveness of two existing spill treating agents meant to disperse spilled oil products was evaluated.
This work is a collaborative effort between the Emergencies Science and Technology
Section, Environment Canada; the Centre for Offshore Oil, Gas and Energy Research, Fisheries and Oceans Canada ; and Canmet ENERGY, Natural Resources Canada. As well as the laboratory and wave-tank experiments, a literature review was conducted to identify knowledge gaps on the physical and chemical properties of conventional and non-conventional heavy oils, and their fate and behaviour in marine environments. The use and effectiveness of oil spill treating agents is
also reviewed for heavy oils. Two diluted bitumen products, Access Western Blend (AWB) and Cold Lake Blend (CLB), were selected for study as the highest-volume products transported by pipeline in Canada for 2012–2013. The physical characteristics and chemical composition of each product were m easured to aid in potential spill preparation and response.
The major results of the studies were:
  • Like conventional crude oil, both diluted bitumen products floated on saltwater (free of sediment), even after evaporation and exposure to light and mixing with water
  • When fine sediments were suspended in the saltwater, high-energy wave action mixed the sediments with the diluted bitumen, causing the mixture to sink or be dispersed as floating tarballs;  The use of the term “tarball” in this report follows convention in the literature and refers to the consistency of floating, heavily-weathered oil. It does not describe the chemical composition of the product.

Internal copy of this report:1633_dilbit_technical_report_e_v2_final-s

The Gainford Study: Done at 15 degrees C??

One of the most infamous reports used by Trans Mountain Pipelines comes from the Gainford study : A Study of Fate and Behaviour of Diluted Bitumen Oils on Marine Waters: See the PDF: http-_www.transmountain.com_uploads_papers_1391734754-astudyoffateandbehaviourofdilutedbitumenoilsonmarinewater

15degreesThe fact that it was done under very artificial conditions has been widely criticized. For me, the fact that they used 15 degrees C was enough to make me very dubious given the fact that Strait of Juan de Fuca waters as measured at Race Rocks now for 90 years has rarely in August risen to 13 degrees C.

 

Ship Noise and its Effect on Killer Whales

In April, 2014 I attended the Salish Sea Ecosystem Conference in Seattle. One of the presentations  which surprized me showed  the risk to the Southern resident Killer Whale populations from Noise Imapcts in the Salish Sra under Commercial shipping growth Scenarios. Following is a reference to Beam Reach which carries a summary presentation of this. — Scott Veirs, Beam Reach Marine Science & Sustainability; Val Veirs, Colorado College; Jason Wood, Sea Mammal Research Unit

soundimpacticonEmazing talk on fossil fuel ship noise & killer whales

This afternoon I’m giving a talk at the 2014 Salish Sea Ecosystem Conference in which I present our estimates of sound pressure levels from commercial ships in Haro Strait, the core of the summertime critical habitat for the Southern Resident killer whales. I also take a first look at noise impacts of the current tanker and bulk carrier fleets and ask how those impacts may change if a suite of proposed fossil fuel export facilities are added to the Salish Sea.

– See more at: http://www.beamreach.org/2014/04/30/emaze-talk-fossil-fuel-ship-noise-killer-whales

Reference#2: Puget Sound Partnership Oil Spill Issues in Washington

This organization has assisted in the production of several studies on Oil Spill Issues which affect Juan de Fuca Strait and the Salish Sea.

http://www.psp.wa.gov/oilspills.php

What is the Puget Sound Partnership doing in 2014 to address oil spill issues in Washington?

The 2009 Washington State Legislature directed the Puget Sound Partnership to provide independent advice and assessment of Washington State’s oil spill programs and make recommendations for any necessary improvements. In late summer 2010 the Partnership assembled a Cross-Partnership Oil Spill Work Group to help assist the Leadership Council carry out this responsibility.

The 2012 Action Agenda outlines the priorities identified by the Work Group in May 2011. Since then the Partnership has promoted activites that concentrate on:

  • vessel traffic risk assessments,
  • reduction of abandoned and derelict vessels, and
  • involvement of locals in oil spill practice drills and assessments of natural resources

USA Reference #1: Vessel Traffic Risk Assessment Synopsis. GWU

This is the first in a series of Risk Assessment publications from US  sources that I will be highlighting here as they have great implications for the risk of oil spills on Metchosin shores:
VTRA 2010–SYNOPSIS OF RMM SCENARIO COMPARISON APPLIED TO CASE T: GW–KM-DP by George Washington University.  Dec 2013

http://www.seas.gwu.edu/~dorpjr/VTRA/PSP/CASES/VTRA%202010%20Master%20Comparison%20-%20T%20-%20RMM.pdf

Dr. J.Rene van Doop and Dr. Jason R.W. Merrick developed a vessel traffic movement baseline based on 2010 data and used that to model predictions for the future given the following projected inceases per year in Tanker Traffic:

487 gateway Bulk Carriers
348 Trans Mountain Pipeline Expansion (Kinder Morgan)
348 Delta Port Carriers
67 Delta Port Container Ships +Bunkering Barges
1250= Total projected increase per year

VTRA

Macroalgae rolls in as the storms increase out in the Strait

This morning’s walk on the beach showed a different pattern of macroalgal drift on the shore.

Alex gathers a rich mix of brown, red and green algae for enriching the garden mulch.

Alex gathers a rich mix of brown, red and green algae for enriching the garden mulch.

East winds of the last two weeks have torn up most of the immediately offshore red and brown algae and have produced drifts of biomass on the beach.
The  local organic farmers have had a good stretch of seaweed gathering as a result.

 

 

 

2014-11-02nereocystisroll

The tangled mass of stipes of Nereocystis leutkeana

Today however, there were rolls of both Macrocystis pyrifera (Giant Kelp) and Nereocystis leutkeana. (our common Bull kelp.)

The Macrocystis prefers growing in water of higher salinity than we have inside the Salish sea, so it supposedly arrives here by coming down the Strait from the West Coast and then ending up on our beaches.  I have seen it growing off Bamfield and it certainly grows down as far as California and was harvested experimentally for Biogas extraction.

Reference From Biotechnology for Biofuels: “Macroalgae as a source of bioenergy first received intensive scrutiny as part of the US Ocean Food and Energy Farm project as proposed by Wilcox [10], initiated in 1973 and lasting over a decade [11]. It resulted in the construction of ocean farms for cultivation of the giant kelp Macrocystis[12]; reviewed by Kelly and Dworjanyn, [13]. While farming this species of seaweed in this truly offshore environment presented many technical challenges, the biogasification of macroalgal biomass gave excellent results [10,12,14,15]. This and subsequent research highlights some of the major advantages of macroalgae over other sources of biofuels (see Table 1).”

2014-11-02 macrocystisrole

A roll of the complete plants of Macrocystis pyrifera

The more usual macroalgae that we get on Taylor Beach is Nereocystis leutkeana. In the 1980’s there was research done on the volumes of biomass that could be derived for energy extraction from kelp around Vancouver Island, but since kelp beds are such a valuable habitat and fish nursery, fortunately those plans have been put on hold.

The small floats. or Pneumatocysts of macroalgae often become detached and turn up on the beach . Here is a comparison of pneumatocysts of three Brown algae species.

2014-11-02 pneumatocysts of three species

Pneumatocysts of egregia menziesii on the left, Nereocytis leutkeana in the middle and two floats of Macrocystis pyrifera on the right.

 The arrival of these macroalgae on the beach starts the process of decomposition which is really the first time that the energy fixed by these rapidly growing macroalgae, with very high rates of productivity, is passed on in the food web.

Surf Scoter (Melanitta perspicillata) off Taylor Beach

surfscoter

Surf Scoter off Taylor Beach: photo by Garry Fletcher

From September on through winter we see flocks of Surf Scoters feeding offshore on Taylor Beach . Today they were 100 metres offshore. They usually do not approach the shore as closely as the grebes and loons.

“The British Columbia Ministry of Environment, Land and Parks (BC Conservation Data Centre 2000) has designated them as a “Blue Listed”  species. Blue List taxa are of special concern because of characteristics that make them particularly sensitive to disturbance from human activities or natural events. Blue-listed taxa are at risk, but are not extirpated, endangered or threatened (Master 1991). “(SFU biology)

A western grebe hangs out with a flock of Surf Scoters

A western grebe hangs out with a flock of Surf scoters

gfscoteroct292014

Surf Scoters on Taylor beach Oct 28, 2014

Scientific classification
Kingdom: Animalia
Phylum: Chordata
Class: Aves
Order: Anseriformes
Family: Anatidae
Subfamily: Merginae
Genus: Melanitta
Species: M. perspicillata